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Visible light-induced photocatalytic performance of green MnFe2O4 and CoFe2O4 nanoparticles | ||
Caspian Journal of Environmental Sciences | ||
مقالات آماده انتشار، اصلاح شده برای چاپ، انتشار آنلاین از تاریخ 22 مهر 1402 اصل مقاله (1.09 M) | ||
نوع مقاله: Research Paper | ||
شناسه دیجیتال (DOI): 10.22124/cjes.2023.7173 | ||
نویسندگان | ||
Mohammad Lotfi1؛ Mortaza Mirzaei* 1؛ Akbar Hassanpour2؛ Hossein Safardoust-Hojaghan3؛ Ali Khani1 | ||
1Department of Chemistry, Miyaneh Branch, Islamic Azad University, Miyaneh, Iran | ||
2Department of Chemistry, Marand Branch, Islamic Azad University, Marand, Iran | ||
3Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran | ||
چکیده | ||
Water photocatalytic treatment has found more attention in recent years. Photocatalytic process can degrade various organic pollutants in water using free solar energy. In this study, manganese ferrite (MnFe2O4) and cobalt ferrite (CoFe2O4) as magnetic photocatalysts were prepared through novel, green and simple co-precipitation route. So, marshmallow extract was applied as green capping agent for morphological engineering of products. The crystalline structure, shape, and particle size of prepared products were characterized via X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques. The cubic phase of the products with sphere-like morphology were formed. The BET analysis revealed that the prepared MnFe2O4 (72.30 m2 g-1) and CoFe2O4 (65.85 m2 g-1) have sufficient surface area for photocatalytic application. The UV-vis diffuse reflectance spectroscopy (DRS) analysis was applied for assessment of the optical properties of these products. The optical band gap of as-obtained MnFe2O4 and CoFe2O4 were 2.42 and 2.71 eV, respectively. Finally, the results indicated that the MnFe2O4 can removed 78, 84, and 92% of methyl orange, methylene blue, and acid violet 7 from water, after 80 min UV irradiation respectively. It was found that the photocatalytic activity of CoFe2O4 is lower than MnFe2O4. Also, the further examination revealed that the photocatalytic efficiency has decreased under visible light irradiation. This study introduces MnFe2O4 and CoFe2O4 as excellent photocatalysts for degradation of organic pollutants. | ||
کلیدواژهها | ||
Magnetic nanomaterials؛ Optical properties؛ Photocatalyst؛ Surface area؛ Water pollutant | ||
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