پیوندهای مفید
آمار
| تعداد نشریات | 31 |
| تعداد شماره‌ها | 709 |
| تعداد مقالات | 6,688 |
| تعداد مشاهده مقاله | 9,256,241 |
| تعداد دریافت فایل اصل مقاله | 6,361,929 |
Enhanced removal of amoxicillin and chlorophenol as a model of wastewater pollutants using hydrogel nanocomposite: Optimization, thermodynamic, and isotherm studies | ||
| Caspian Journal of Environmental Sciences | ||
| دوره 21، شماره 2، تیر 2023، صفحه 411-422 اصل مقاله (1.31 M) | ||
| نوع مقاله: Research Paper | ||
| شناسه دیجیتال (DOI): 10.22124/cjes.2023.6535 | ||
| نویسندگان | ||
| Aseel M. Aljeboree* 1؛ Zainab D. Alhattab2؛ Usama S. Altimari3؛ Ahmed Kareem Obaid Aldulaim4؛ Asmaa Kefah Mahdi5؛ Ayad F. Alkaim1 | ||
| 1Department of Chemistry, College of Sciences for W, University of Babylon, Hilla, Iraq | ||
| 2Ministry of Interior Affairs, Babylon Police Command, Criminal Evidence Investigation Department, Iraq | ||
| 3Department of Medical Laboratories Technology, AL-Nisour University College, Baghdad, Iraq | ||
| 4Department of Pharmacy, Al-Zahrawi University College, Karbala, Iraq | ||
| 5National University of Science and Technology, Dhi Qar, Iraq | ||
| چکیده | ||
| Studies have been conducted to gain understandings and generic knowledge of the equilibrium aspects of adsorption of different adsorbents, SA-Bn-TiO2 NPs surfaces. Removal of two pollutants, Amoxicillin drug AMX, 4-chlorophenol (CPH) from aqueous solutions by adsorption with SA-Bn-TiO2 NPs, SA-Bn and TiO2 NPs surfaces were experimentally determined. The best results were found at pH 6.6, temperature 30 ºC, and adsorbent dosage of 0.05 g of SA-Bn-TiO2 NPs for both studying adsorption capacity and removal percentage. The morphology and structure of the SA-Bn-TiO2 NPs hydrogel beads were investigated utilizing Ultraviolet-Visible Spectroscopy (UV–Vis), Fourier Transform Infrared (FT-IR), Thermo gravimetric analysis (TGA), Field Emission Scanning Electron Microscopy (FE-SEM), Transmission Electron Microscopy (TEM), Energy Dispersive X-Ray (EDX) and X-ray Diffraction Spectroscopy (XRD). The best contact time for equilibrium reached one hour. It is essentially due to saturation of the active site which does not let further adsorption to take place. For the two pollutants onto hydrogel, best adsorption was found to be at pH 11, and adsorption raised by increase in the pH solution. The value negative of ∆G confirmed that the nature adsorption process is spontaneous. The value positive of ∆S confirmed the raise randomness at the solid-solution interface pending adsorption and the value positive of ∆H confirmed that adsorption process is endothermic. | ||
| کلیدواژه‌ها | ||
| Hydrogel؛ Drug؛ Endothermic؛ Spontaneous؛ Amoxicillin؛ 4-Chlorophenol | ||
| مراجع | ||
|
Aguzzi, C, Capra, P, Bonferoni, C, Cerezo, P, Salcedo, I, Snchez, R, Caramella, C & Viseras, C 2020, Chitosanâ silicate biocomposites to be used in modified drug release of 5-aminosalicylic acid (5-ASA). Applied Clay Science, 50: 106-111.
Al Niaeem, HS & Hanoosh, W 2022, Preparation of semi ipns-hydrogel composite for removing congo red and bismarck brown y from wastewater: kinetic and thermodynamic study. Egyptian Journal of Chemistry, 56: 19-34.
Aljeboree, AM & Alkaim, AF 2019, Role of plant wastes as an eco-friendly for pollutants (crystal violet dye) removal from aqueous solutions. Plant Archives, 19: 902-905.
Aljeboree, AM, Alshirifi, AN & Alkaim, AF 2019, Activated carbon (as a waste plant sources)-clay micro/nanocomposite as effective adsorbent: Process optimization for ultrasound-assisted adsorption removal of amoxicillin drug. Plant Archives, 19: 915-919.
Aljeboree, AM, et al. 2019, Photocatalytic degradation of textile dye crystal violet wastewater using zinc oxide as a model of pharmaceutical threat reductions. Journal of Global Pharma Technology, 11:138-143.
Alkaim, AF & Ajobree, AM 2020, White marble as an alternative surface for removal of toxic dyes (Methylene blue) from Aqueous solutions. International Journal of Advanced Science and Technology, 29: 5470-5479.
Alqaragully, MB et al. 2015, Monoethanolamine: Production plant. Research Journal of Pharmaceutical, Biological and Chemical Sciences, 6: 1287-1296.
Amer, M, Alshamri, AM, Alqaragully, MB & Alkaim, AF 2021, Removal of toxic textile dyes from aqueous solution through adsorption onto coconut husk waste: Thermodynamic and isotherm studies. Caspian Journal of Environmental Sciences, 19: 513-522
Chkirid, S, Zari, N, Achour, R, Hassoune, H, Lacheha, A, Qaiss, AeL & Bouhfid, R, Highly synergic adsorption/photocatalytic efficiency of Alginate/Bentonite impregnated TiO2 beads for wastewater treatment Journal of Photochemistry and Photobiology A: Chemistry, 412: 113215.
Dhiman, J, Prasher, SO, ElSayed, E, Patel, RM, Nzediegwu, Ch & Mawof, A 2020, Heavy metal uptake by wastewater irrigated potato plants grown on contaminated soil treated with hydrogel based amendments. Environmental Technology & Innovation, 19:100952.
Freundlich, HW 1939, The Adsorption of cis- and trans-Azobenzene Journal of the American Chemical Society, 1939. 61: 2228-2230.
Gulin Selda Pozan, AK 2014, Significant enhancement of photo catalytic activity over bifunctional ZnO-TiO2 catalysts for 4-chlorophenol degradation. Chemosphere, 105: 152-159.
Jawad, MA & Radia, ND 2021, Role of Sodium Alginate-g-poly (Acrylic acid-fumaric acid) Hydrogel for Removal of Pharmaceutical Paracetamol from Aqueous Solutions by Adsorption International Journal of Pharmaceutical Quality Assurance, 12: 202-205.
Jiang, W, Guo, X, Yang, M, Lu, Y, Wang, Y, Zheng, Y & Wei, G 2019, Adsorption of cationic dye from water using an iron oxide/activated carbon magnetic composites prepared from sugarcane bagasse by microwave method. Environmental Technology, 2 p. DOI: 10.1080/09593330.
Jun, LY, Yon, LS, Mubarak, NM, Bing, ChH, Pan, Sh, Danquah, MK, Abdullah, EC & Khalid, M 2019, An overview of immobilized enzyme technologies for dye and phenolic removal from wastewater. Journal of Environmental Chemical Engineering, 7:102961.
Kamil, AM, Mohammed, HT, Alkaim, AF & Hussein, FH 2016, Adsorption of Congo red on multiwall carbon nanotubes: Effect of operational parameters. Journal of Chemical and Pharmaceutical Sciences, 9: 1128-1133.
Karimi Maleh, H, Tahernejad Javazmi, F, Gupta, VK, Ahmar, H, Asadi, MH 2020, A novel biosensor for liquid phase determination of glutathione and amoxicillin in biological and pharmaceutical samples using a ZnO/CNTs nanocomposite/catechol derivative modified electrode. Journal of Molecular Liquids, 196: 258-263.
Kevadiya, BD, Joshi, GhV, Mody, HM & Hari, C 2021, Bajaj Biopolymer–clay hydrogel composites as drug carrier: Host–guest intercalation and in vitro release study of lidocaine hydrochloride. Applied Clay Science, 52: 364-367.
Kim, YS & Kim, JH 2019, Isotherm, kinetic and thermodynamic studies on the adsorption of paclitaxel onto Sylopute. The Journal of Chemical Thermodynamics, 130: 104-113.
Kumar, NS, Poulose, AM, Suguna, M & Al Hazza, MI 2019, Equilibrium and kinetic studies of biosorptive removal of 2,4,6-trichlorophenol from aqueous solutions using untreated agro-waste pine cone biomass. Processes, 1: 22-33.
Langmuir, I 1918, The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society, 40: 1361-1403.
Liu, Y, Chen, Y, Yahui Shi, Y, Wan, D, Chen, J & Xiao, Sh 2019, Adsorption of toxic dye Eosin Y from aqueous solution by clay/carbon composite derived from spent bleaching earth. Journal of Hazardous Materials, 1: 4656-5544.
Luo, Q, Ren, T, Lei, Z, Huang, Y, Huang, Y, Xu, D, Wan, C, Guo, X & Wu, Y 2022, Non-toxic chitosan-based hydrogel with strong adsorption and sensitive detection abilities for tetracycline Chemical Engineering Journal, 427: 131738.
Malatji, N, Makhado, E, Modibane, KD, Ramohlola, KE, Maponya, TC, Monama, GR & Hato, MJ 2021, Removal of methylene blue from wastewater using hydrogel nanocomposites: A review. Nanomaterials and Technologies for Environmental Applications, 11: 1-27.
Mittal, H & Ray, SS 2019, A study on the adsorption of methylene blue onto gum ghatti/TiO2 nanoparticles-based hydrogel nanocomposite. International Journal of Biological Macromolecules, 88: 66-80.
Mittal, H, Alili, AA, Morajkar, PP & Alhassan, SM 2021, Graphene oxide crosslinked hydrogel nanocomposites of xanthan gum for the adsorption of crystal violet dye. Journal of Molecular Liquids, 323: 115034.
Moussavi, G, Alahabadi, A,Yaghmaeian, K, Eskandari, M 2020, Preparation, characterization and adsorption potential of the NH4Cl-induced activated carbon for the removal of amoxicillin antibiotic from water. Chemical Engineering Journal, 217: 119-128.
Nasseh, N, Barikbin, B,Taghavi, L & Nasseri, MA 2019, Adsorption of metronidazole antibiotic using a new magnetic nanocomposite from simulated wastewater (isotherm, kinetic and thermodynamic studies). Composites Part B: Engineering, 159: 146-156.
Osman, AM, Hendi, AH & Saleh, TA 2020, Simultaneous adsorption of dye and toxic metal ions using an inter-facially polymerized silica/polyamide nanocomposite: Kinetic and thermodynamic studies. Journal of Molecular Liquids, 314: 113640.
Sakin, O, Mohmmad, AH, Belal, HM & Arbi, M 2019, Adsorption thermodynamics of cationic dyes (methylene blue and crystal violet) to a natural clay mineral from aqueous solution between 293.15 and 323.15 K. Arabian Journal of Chemistry, 11: 615-623.
Tariq, J. AlMusawi, NM, Taghavi, M, Mohebi, S & Balarak, D 2021, Activated carbon derived from Azolla fliculoides fern: a high adsorption capacity adsorbent for residual ampicillin in pharmaceutical wastewater. Biomass Conversion and Biorefinery, https://doi.org/10.1007/s13399-021-01962-4.
Thakur, S 2017, Synthesis, characterization and adsorption studies of an acrylic acid-grafted sodium alginate-based TiO2 hydrogel nanocomposite. Adsorption Science & Technology, 36(1-2): 458-477, DOI: 10.1177/0263617417700636
Xiong, J et al. 2020, Hexagonal boron nitride adsorbent: Synthesis, performance tailoring and applications. Journal of Energy Chemistry, 40: 99-111.
Yasin, AS, Kim, DH & Lee, K 2021, One-pot synthesis of activated carbon decorated with ZnO nanoparticles for capacitive deionization application. Journal of Alloys and Compounds, 870: 159422.
Ying, Zh, Yu, Ch, Jian, Zh, Zongrui, T & Shaohua, J 2020, Preparation of SA-g-(PAA-co-PDMC) polyampholytic superabsorbent polymer and its application to the anionic dye adsorption removal from effluents. Ultrasonics Sonochemistry, 5: 12-18.
Yu, F, Li, Y, Han, Sh & Jie, M 2019, Adsorptive removal of antibiotics from aqueous solution using carbon materials. Chemosphere, 153: 365-385.
Zaheer, Z, Al Asfar, A & Aazam, E 2019, Adsorption of methyl red on biogenic Ag@Fe nanocomposite adsorbent: Isotherms, kinetics and mechanisms. Journal of Molecular Liquids, 283: 287-298.
Zhao, Sh, Zhan, Y, Wan, X, SHe, SH,Yang, X, JHu, J & Zhang, G 2020, Selective and efficient adsorption of anionic dyes by core/shell magnetic MWCNTs nano-hybrid constructed through facial polydopamine tailored graft polymerization: Insight of adsorption mechanism, kinetic, isotherm and thermodynamic study. Journal of Molecular Liquids, 319: 1-6. | ||
|
آمار تعداد مشاهده مقاله: 285 تعداد دریافت فایل اصل مقاله: 370 |
||