|تعداد مشاهده مقاله||7,855,553|
|تعداد دریافت فایل اصل مقاله||6,018,852|
Multivariate and geostatistical analysis of spatial distribution and potential sources of heavy metals in surface waters
|Caspian Journal of Environmental Sciences|
|مقاله 3، دوره 17، شماره 1، خرداد 2019، صفحه 23-41 اصل مقاله (1.12 M)|
|نوع مقاله: Research Paper|
|شناسه دیجیتال (DOI): 10.22124/cjes.2019.3341|
|Mohammad Rafiee1؛ Akbar Eslami1؛ Reza Saeedi2؛ Mehrnoosh Abtahi3؛ Mahsa Jahangiri rad* 4|
|1Environmental and Occupational Hazards Control Research Center, Shahid Beheshti University of Medical Sciences, Tehran, Iran|
|2Department of Health Sciences, Faculty of Health, Safety and Environment, Shahid Beheshti University of Medical Sciences, Tehran, Iran|
|3Department of Environmental Health Engineering, School of Public Health, Shahid Beheshti University of Medical Sciences, Tehran, Iran|
|4Water purification research center, Tehran Medical Sciences, Islamic Azad University, Tehran, Iran|
|Although economic growth from industrialization has improved health and quality of life indicators, however, it has intensified the release of chemicals into the environment, with severe effects on health. The present work confers toxic metals contamination levels of surface waters in Zanjan Province, Iran, encompassing several rich mines of lead and zinc. The soluble concentrations of Fe, Cu, Cd, Ni, Pb, Zn and AS in water samples were determined using ICP-MS and the level of contamination was appraised by heavy metal pollution index (HPI). Multivariate statistical methods comprising Pearson’s correlation analysis, hierarchical cluster analysis, and principal component analysis were applied to evaluate the relationships between heavy metals. Geostatistical analyses were carried out to conduct the distribution characteristics and the sources of pollution. The results showed that concentrations of studied heavy metals were higher in the spring compared to the winter, however, the calculated HPI values did not exceed the limit of 15. Anthropogenic activities, for the most part, control the quality of water in this study area with minor natural/geogenic input. All the measured heavy metals were strongly homologous in spring based on correlation coefficients. However, this correlation gets weaker in the winter due to a degree of heterogeneity between Zn, Cd, As and other elements. Distribution pattern of the heavy metals pollution index of surface waters with different land uses decreased in the order of: agricultural>dry farming/water bodies>built up areas>forest areas. Multi hotspots for the above mentioned heavy metals were located in the southeast study areas.|
|Water Quality؛ Heavy metal pollution index؛ Geostatistics؛ Spatial distribution|
Adams, WJ, Kimerle, RA & Barnett, JW 1992, Sediment quality and aquatic life assessment. Environmental Science and Technology, 26: 1865–1875.
Atafar, Z, Mesdaghinia, A, Nouri, J, Homaee, M, Yunesian, M & Ahmadimoghaddam, M 2010, Effect of fertilizer application on soil heavy metal concentration. Environmental Monitoring and Assessment, 160: 83–89.
Astel, A, Tsakovski, S, Barbieri, P & Simeonov, V 2007, Comparison of self-organizing maps classiﬁcation approach with cluster and principal components analysis for large environmental data sets. Water Research, 41: 4566–4578.
ATSDR 2005, U.S. Department of health and human services, Agency for toxic substances and disease registry.
Cai, L, Xu, Z, Ren, M, Guo, Q, Hu, X Hu, G, Wan, H & Peng, P 2012, Source identification of eight hazardous heavy metals in agricultural soils of Huizhou, Guangdong Province, China. Ecotoxicology and Environmental Safety, 78: 2–8.
Cempel, M & Nikel, G 2006, Nickel: a review of its sources and environmental toxicology. Polish Journal of Environmental Studies, 15: 375–382.
Chehregani, A, Noori, M & Yazdi, H 2009, Phytoremediation of heavy-metal-polluted soils: Screening for new accumulator plants in Angouran mine (Iran) and evaluation of removal ability. Ecotoxicology and Environmental Safety, 72: 1349 - 1353.
Chen, YF 2011, Review of the research on heavy metal contamination of China’s city soil and its treatment method. China Population, Resources and Environment, 21: 536-539.
Cheng, H & Hu, Y 2010, Lead (Pb) isotopic fingerprinting and its applications in lead pollution studies in China: a review. Environmental Pollution, 158: 1134–1146.
Delavar, MA & Safari, Y 2016, Spatial distribution of heavy metals in soils and plants in Zinc Town, northwest Iran. International Journal Environmental Science Technology, 13: 297–306.
Goovaerts, P 1999, Geostatistics in soil science: State of the art and perspectives. Geoderma, 89: 1-45.
Hani, A & Pazira, E 2011, Heavy metals assessment and identification of their sources in agricultural soils of Southern Tehran, Iran. Environmental Monitoring and Assessment, 176: 677–691.
Horton, PK 1965, An index-number system for rating water quality. Journal of the Water Pollution Control Federation, 37: 300–06.
Hu, Y, Liu, X, Bai, J, Shih, K, Zeng, EY & Cheng, H 2013, Assessing heavy metal pollution in the surface soils of a region that had undergone three decades of intense industrialization and urbanization. Environmental Science and Pollution Research, 20: 6150–6159.
Kohušová, K, Havel, L, Vlasák, P & Tonika, J 2011, A long term survey of heavy metals and specific organic compounds in biofilms, sediments, and surface water in a heavily affected river in the Czech Republic. Environmental Monitoring and Assessment. 174: 555–572.
Kramer, RL 1976, Effects of century old Missouri Lead mining operations upon the water quality sediments, and biota of Flat River Creek, M.S. Thesis, University of Missouri, Rolla, Missouri.
Li, S & Zhang, Q 2010, Risk assessment and seasonal variations of dissolved trace elements and heavy metals in the Upper Han River, China. Journal of Hazardous Materials, 181(1): 1051–1058.
Lin, HJ, Sunge, T, Cheng, CY, Guo & HR 2013, Arsenic levels in drinking water and mortality of liver cancer in Taiwan. Journal of Hazardous Materials, 262:1132-8.
Lu, RK, Xiong, LM & Shi, ZY 1992, A review about studies on cadmium in soil-crop ecosystem. Soils, 24: 129–132 (In Chinese).
Madani, K 2014, Water management in Iran: what is causing the looming crisis? Journal of Environmental Studies and Sciences, 4: 315–328
Mohammadian, M, Nouri, J, Afshari, N, Nassiri, J & Nourian, M 2008, Investigation of heavy metals concentrations in the water wells Close to Zanjan zinc and lead smelting plant. Iranian journal of health and environment, 1: 51-56.
Mohan, SV, Nithila, P, Reddy & SJ 1996, Estimation of heavy metal in drinking water and development of heavy metal pollution index. Journal of Environmental Science and Health, Part A, 31: 283–289.
Naderi, A, Delavar, MA, Kaboudin, B & Askari, MS 2017, Assessment of spatial distribution of soil heavy metals using ANN-GA, MSLR and satellite imagery. Environmental Monitoring and Assessment, 189(5): 214-220.
Ozmen, H, Kulahci, F, Cukurovali, A & Dogru, M 2004, Concentrations of heavy metal and radioactivity in surface water and sediment of Hazar Lake (Elazig, Turkey). Chemosphere, 55(3): 401–408
Panigrahy, BP, Singh, PK, Tiwari, AK, Kumar, B & Kumar, A 2015, Assessment of heavy metal pollution index for groundwater around Jharia coalfield region, India. Journal of Biodiversity and Environmental Sciences, 6: 33–39.
Parameters of water quality. Interpretation and Standards. Environmental Protection Agency (EPA) 2001. Published by the Environmental Protection Agency, Ireland.
Parizanganeh, A, Hajisoltani, P & Zamani, A 2010, Assessment of heavy metal pollution in surficial soils surrounding Zinc Industrial Complex in Zanjan-Iran. Procedia Environmental Sciences, 2: 162-166.
Rodriguez Martin, JA, Ramos-Miras, JJ, Boluda, R & Gil, C 2013, spatial relations of heavy metals in arable and greenhouse soils of a Mediterranean environment region (Spain). Geoderma, 200-201: 180-188.
Rodríguez, JA, Nanos, N, Grau, JM, Gil, L & López-Arias, M 2008, Multiscale analysis of heavy metal contents in Spanish agricultural topsoil. Chemosphere, 70: 1085–1096.
Schmitt, CJ & Finger, SE 1982, The dynamics of metals from past and present mining activities in the big and black river watersheds, Southeastern Missouri. U.S., Fish and Wildlife Service. Columbia National Fisheries Research Laboratory. Columbia, USA.
Schwarzenbach, RP, Egli, T, Hofstetter, TB, von Gunten, U & Wehrli, B 2010, Global Water Pollution and Human Health. Annual Review of Environment and Resources, 35: 109–136.
Shannon, MA, Bohn, PW, Elimelech, M, Georgiadis, JG, Marin, BJ & Mayes, AM 2008, Science and technology for water purification in the coming decades. Nature, 452.
Simeonova, P & Simeonov, V 2007, Chemometrics to evaluate the quality of water sources for human consumption. Microchimica Acta, 156: 315–320.
Sun, YB, Zhou, QX, Xie, XK & Liu, R 2010, Spatial, sources and risk assessment of heavy metal contamination of urban soils in typical regions of Shenyang, China. Journal of Hazardous Materials, 174: 455-462.
Tiwari, AK, Maio, MD, Singh, PK & Mahato, MK 2015, Evaluation of Surface Water Quality by Using GIS and a Heavy Metal Pollution Index (HPI) Model in a Coal Mining Area, India. Bulletin of Environmental Contamination and Toxicology, 95: 304–310.
US EPA 2000, Supplementary guidance for conducting health risk assessment of chemical mixtures, Risk Assessment Forum Technical Panel.
Zamani, AA, Yaftian, MR & Parizanganeh, A 2012, Multivariate statistical assessment of heavy metal pollution sources of groundwater around a lead and zinc plant. Journal of Environmental Health Science and Engineering, 9: 29-36.
Zamani, AA, Yaftian, MR & Parizanganeh, A 2015, Statistical evaluation of topsoil heavy metal pollution around a lead and zinc production plant in Zanjan province, Iran. Caspian journal of environmental sciences, 13(4): 349-361.
Zhang, J, Mauzerall, DL, Zhu, T, Liang, S, Ezzati, M & Remais, JV 2010, Environmental health in China: progress towards clean air and safe water. Lancet, 375: 1110–1119.
Zhou, JM, Dang, Z, Cai, MF & Liu, CQ 2007, Soil heavy metal pollution around the Dabaoshan Mine, Guangdong Province, China. Pedosphere, 17: 588–594.
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