تعداد نشریات | 31 |
تعداد شمارهها | 738 |
تعداد مقالات | 6,952 |
تعداد مشاهده مقاله | 9,878,269 |
تعداد دریافت فایل اصل مقاله | 6,706,618 |
ارزیابی یک روش کچرز اصلاحشده جهت استخراج دیازینون و ادیفنفوس از دو خاک مختلف شالیزارهای برنج با استفاده از HPLC-UV | ||
تحقیقات آفات گیاهی | ||
مقاله 3، دوره 7، شماره 1، خرداد 1396، صفحه 13-28 اصل مقاله (1.11 M) | ||
نوع مقاله: مقاله پژوهشی | ||
شناسه دیجیتال (DOI): 10.22124/iprj.2017.2267 | ||
نویسندگان | ||
احسان ترابی1؛ خلیل طالبی جهرمی* 1؛ احمدعلی پور بابایی2؛ مسعود احمدزاده1 | ||
1گروه گیاهپزشکی، پردیس کشاورزی و منابع طبیعی دانشگاه تهران، کرج، ایران | ||
2گروه خاکشناسی، پردیس کشاورزی و منابع طبیعی دانشگاه تهران، کرج، ایران | ||
چکیده | ||
در این پژوهش، کارایی استخراج دیازینون و ادیفنفوس از دو خاک شالیزار با درصدهای ماده آلی متفاوت توسط یک روش کچرز اصلاحشده بررسی شد. روشها شامل استخراج 10 گرم خاک با استونیتریل بدون افزودن و همراه با افزودن آب به نمونهها، استخراج 5 گرم خاک با استونیتریل همراه با افزودن آب به نمونهها و استخراج 5 گرم خاک با اتیل استات همراه با افزودن آب به نمونهها بودند. خالصسازی به کمک روش استخراج فاز جامد پخش شونده انجام شد. اندازهگیری کمی آفتکشها با استفاده از کروماتوگرافی مایع و آشکارساز فرابنفش/مرئی صورت گرفت. بر اساس نتایج، درصد ماده آلی خاک تأثیر معنیداری بر کارایی استخراج دو آفتکش داشت. عواملی همچون کاهش حجم نمونه و افزودن آب به آن پیش از استخراج و استفاده از اتیل استات بهعنوان حلال تأثیر معنیداری در افزایش کارایی استخراج داشتند. بهترین درصدهای بازیابی (70 تا 110 درصد) و انحراف معیار نسبی (کمتر از 20 درصد) با استفاده از استخراج 5 گرم خاک توسط اتیل استات به همراه افزودن آب به نمونهها به دست آمد. نتایج کالیبراسیون حاکی از خطی بودن این روش در محدوده غلظتهای 5/0 تا 10 میکروگرم بر گرم بود. حساسیت مناسب روش برای دو آفتکش در دو خاک با توجه به مقادیر حد تشخیص و کمی شدن تخمینی (07/0 تا 54/0 میکروگرم بر گرم) تأیید شد. | ||
کلیدواژهها | ||
دیازینون؛ ادیفنفوس؛ کچرز؛ بازیابی؛ منحنی کالیبراسیون | ||
مراجع | ||
Álvarez, M., Du Mortier, C. and Cirelli, A. F. 2013. Behavior of insecticide chlorpyrifos on soils and sediments with different organic matter content from Provincia de Buenos Aires, República Argentina. Water, Air, and Soil Pollution 224(3): 1-6.
Anastassiades, M. 2008. QuEChERS a mini-multiresidue method for the analysis of pesticide residues in low-fat products. Stuttgart: Chemisches und Veterin aruntersuchungsamt.
Anastassiades, M., Lehotay, S. J., Štajnbaher, D. and Schenck, F. J. 2003. Fast and easy multiresidue method employing acetonitrile extraction/partitioning and “dispersive solid-phase extraction” for the determination of pesticide residues in produce. Journal of AOAC International 86(2): 412-431.
Boivin, A., Cherrier, R. and Schiavon, M. 2005. A comparison of five pesticides adsorption and desorption processes in thirteen contrasting field soils. Chemosphere 61(5): 668–676.
Colman, A. and Pulford, B. 2006. A crash course in SPSS for Windows: updated for versions 10, 11, 12 and 13. Blackwell Publishers, Inc.
Coquet, Y. 2002. Variation of pesticide sorption isotherm in soil at the catchment scale. Pest Management Science 59(1): 69–78.
Corley, J. 2003. Best practices in establishing detection and quantification limits for pesticide residues in foods. In Lee, P. W., Aizawa, H., Barefoot, A. C. and Murphy, J. J. (Eds), Handbook of residue analytical methods for agrochemicals. Wiley, Chichester. pp. 59–75.
Correia‐Sá, L., Fernandes, V. C., Carvalho, M., Calhau, C., Domingues, V. F. and Delerue‐Matos, C. 2012. Optimization of QuEChERS method for the analysis of organochlorine pesticides in soils with diverse organic matter. Journal of Separation Science 35(12): 1521-1530.
Cruz, S., Lino, C. and Silveira, M. I. 2003. Evaluation of organochlorine pesticide residues in human serum from an urban and two rural populations in Portugal. Science of the Total Environment 317(1): 23-35.
Damalas, C. A. 2009. Understanding benefits and risks of pesticide use. Research and Essays 4(10): 945-949.
Dashtbozorgi, Z., Ramezani, M. K. and Waqif-Husain, S. 2012. Evaluation of matrix effects in gas chromatography mass spectrometry pesticide-residue analysis using QuEChERS sample preparation technique. International Journal of Chemistry 33 (10): 326-332.
Dashtbozorgi, Z., Ramezani, M. K. and Waqif-Husain, S. 2013a. Optimization and validation of a new pesticide residue method for cucumber and tomato using acetonitrile-based extraction-dispersive liquid–liquid microextraction followed by liquid chromatography-tandem mass spectrometry. Analytical Methods 5(5): 1192-1198.
Dashtbozorgi, Z., Ramezani, M. K. and Waqif-Husain, S. and Broumand, P. 2013b. Validation of matrix matched calibration for analysis of insecticide and fungicide residues in cucumber and tomato using QuEchERS sample preparation followed by gas chromatography-mass spectrometry. Journal of the Chilean Chemical Society 58: 1701-1705
Day, P. R. 1965. Particle fractionation and particle-size analysis. In Black, C. A., Evans, D. D., Ensminger, L. E., White, J. L., Clark, P. E. and Dinauer, R. C. (Eds.), Methods of Soil Analysis. American Society of Agronomy, Madison, USA. pp. 545–567.
Diez, C., Traag, W. A., Zommer, P., Marinero, P. and Atienza, J. 2006. Comparison of an acetonitrile extraction/partitioning and “dispersive solid-phase extraction” method with classical multi-residue methods for the extraction of herbicide residues in barley samples. Journal of Chromatography A 1131(1): 11-23.
Fernandes, V. C., Subramanian, V., Mateus, N., Domingues, V. F. and Delerue-Matos, C. 2012. The development and optimization of a modified single-drop microextraction method for organochlorine pesticides determination by gas chromatography-tandem mass spectrometry. Microchimica Acta 178(1-2): 195-202.
Fernandez-Alvarez, M., Llompart, M., Lamas, J. P., Lores, M., Garcia-Jares, C., Cela, R. and Dagnac, T. 2008. Simultaneous determination of traces of pyrethroids, organochlorines and other main plant protection agents in agricultural soils by headspace solid-phase microextraction–gas chromatography. Journal of Chromatography A 1188(2): 154-163.
Gamón, M., Sáez, E., Gil, J. and Boluda, R. 2003. Direct and indirect exogenous contamination by pesticides of rice-farming soils in a Mediterranean wetland. Archives of Environmental Contamination and Toxicology 44(2): 0141-0151.
Gevao, B., Semple, K. T. and Jones, K. C. 2000. Bound pesticide residues in soils: a review. Environmental Pollution 108(1): 3-14.
Gonçalves, C., Carvalho, J. J., Azenha, M. A. and Alpendurada, M. F. 2006. Optimization of supercritical fluid extraction of pesticide residues in soil by means of central composite design and analysis by gas chromatography–tandem mass spectrometry. Journal of Chromatography A 1110(1): 6-14.
Gouma S. 2009. Biodegradation of mixtures of pesticides by bacteria and white rot fungi. Ph.D. thesis. School of Health, Cranfield University.
Hornsby, A. G., Wauchope, R. D. and Herner, A. 1995. Pesticide Properties in the Environment. Springer Science and Business Media.
Hu, J. Y., Zhen, Z. H. and Deng, Z. B. 2011. Simultaneous determination of acetochlor and propisochlor residues in corn and soil by solid phase extraction and gas chromatography with electron capture detection. Bulletin of Environmental Contamination and Toxicology 86(1): 95-100.
Hussen, A., Westbom, R., Megersa, N., Mathiasson, L. and Björklund, E. 2006. Development of a pressurized liquid extraction and clean-up procedure for the determination of α-endosulfan, β-endosulfan and endosulfan sulfate in aged contaminated Ethiopian soils. Journal of Chromatography A. 1103(2): 202-210.
Ivdra, N., Herrero-Martín, S. and Fischer, A. 2014. Validation of user-and environmentally friendly extraction and clean-up methods for compound-specific stable carbon isotope analysis of organochlorine pesticides and their metabolites in soils. Journal of Chromatography A 1355: 36-45.
Lehotay, S. J., Kok, A. D., Hiemstra, M. and Bodegraven, P. V. 2005. Validation of a fast and easy method for the determination of residues from 229 pesticides in fruits and vegetables using gas and liquid chromatography and mass spectrometric detection. Journal of AOAC International 88(2): 595-614.
Lesueur, C., Gartner, M., Mentler, A. and Fuerhacker, M. 2008. Comparison of four extraction methods for the analysis of 24 pesticides in soil samples with gas chromatography–mass spectrometry and liquid chromatography–ion trap–mass spectrometry. Talanta 75(1): 284-293.
Li, Y., Dong, F., Liu, X., Xu, J., Li, J., Kong, Z. and Zheng, Y. 2011. Simultaneous enantioselective determination of fenbuconazole and its main metabolites in soil and water by chiral liquid chromatography/tandem mass spectrometry. Journal of Chromatography A. 1218(38): 6667-6674.
Maštovská, K. and Lehotay, S. J. 2004. Evaluation of common organic solvents for gas chromatographic analysis and stability of multiclass pesticide residues. Journal of Chromatography A 1040(2): 259-272.
Paíga, P., Morais, S., Correia, M., Alves, A. and Delerue-Matos, C. 2008. A multiresidue method for the analysis of carbamate and urea pesticides from soils by microwave-assisted extraction and liquid chromatography with photodiode array detection. Analytical Letters 41(10): 1751-1772.
Pinto, C. G., Laespada, M. E. F., Martín, S. H., Ferreira, A. M. C., Pavón, J. L. P. and Cordero, B. M. 2010. Simplified QuEChERS approach for the extraction of chlorinated compounds from soil samples. Talanta 81(1): 385-391.
Ramezani, M. K. and Shahriari, D. 2015. Dissipation behaviour, processing factors and risk assessment for metalaxyl in greenhouse‐grown cucumber. Pest Management Science 71(4): 579-583.
Rashid, A., Nawaz, S., Barker, H., Ahmad, I. and Ashraf, M. 2010. Development of a simple extraction and clean-up procedure for determination of organochlorine pesticides in soil using gas chromatography–tandem mass spectrometry. Journal of Chromatography A 1217(17): 2933-2939.
Shalaby, S. E. M. and Abdou, G. Y. 2010. The influence of soil microorganisms and bio- or - organic fertilizers on dissipation of some pesticides in soil and potato tube. Journal of Plant Protection Research 50 (1): 86-92.
Spark, K. M. and Swift, R. S. 2002. Effect of soil composition and dissolved organic matter on pesticide sorption. Science of the Total Environment 298(1): 147-161.
Tabrizi, A. A, NourMohammadi, G. and Mobasser, H. R. 2015. Effects of different cropping systems on fertility of paddy soil. Journal of Crop Ecophysiology 9(2): 191-202 (In Farsi).
Tomlin, C. D. S. 2011. The Pesticide Manual: A World Compendium (15th ed). CABI.
Tor, A., Aydin, M. E. and Özcan, S. 2006. Ultrasonic solvent extraction of organochlorine pesticides from soil. Analytica Chimica Acta 559(2): 173-180.
Wang, J., Zhao, L., Li, X., Jiang, Y., Li, N., Qin, Z. and Pan, C. 2011. Residue dynamic of pyrimorph on tomatoes, cucumbers and soil under greenhouse trails. Bulletin of Environmental Contamination and Toxicology 86(3): 326-330.
Wang, W., Meng, B., Lu, X., Liu, Y. and Tao, S. 2007. Extraction of polycyclic aromatic hydrocarbons and organochlorine pesticides from soils: a comparison between Soxhlet extraction, microwave-assisted extraction and accelerated solvent extraction techniques. Analytica Chimica Acta 602(2): 211-222.
Yoshida, N., Castro, M., Du Mortier, C. and Cirelli, A. F. 2007. Environmental behavior of antibiotic monensin: preliminary studies in Argentina. Environmental Chemistry Letters 5(3): 157-160.
Zhang, N., Yang, Y., Tao, S., Liu, Y. and Shi, K. L. 2011. Sequestration of organochlorine pesticides in soils of distinct organic carbon content. Environmental Pollution 159(3): 700-705.
| ||
آمار تعداد مشاهده مقاله: 1,785 تعداد دریافت فایل اصل مقاله: 1,356 |