پیوندهای مفید
آمار
| تعداد نشریات | 32 |
| تعداد شمارهها | 856 |
| تعداد مقالات | 8,304 |
| تعداد مشاهده مقاله | 52,789,616 |
| تعداد دریافت فایل اصل مقاله | 9,220,035 |
Diatomite as a natural sorbent for water treatment: A modern review and prospects for application | ||
| Caspian Journal of Environmental Sciences | ||
| دوره 24، شماره 2، تیر 2026، صفحه 595-605 اصل مقاله (786.05 K) | ||
| نوع مقاله: Reviewers | ||
| شناسه دیجیتال (DOI): 10.22124/cjes.2026.9637 | ||
| نویسندگان | ||
| Gulfairus Bizhanova1؛ Laura Kurbanova* 1؛ Elmira Boribay2؛ Bayan Tussupova* 1؛ Olga Zubova1؛ Sabyrzhan Sarsenbayev3؛ Assem Satimbekova4 | ||
| 1Al-Farabi Kazakh National University, Faculty of Geography and Environmental Sciences, UNESCO Chair for Sustainable Development, Almaty, Kazakhstan | ||
| 2Narxoz University, Department of Ecology, Almaty, Kazakhstan | ||
| 3Satbayev University, Mining and Metallurgical Institute named after O.A. Baikonurov, "Chemical Processes and Industrial Ecology" Department, Almaty, Kazakhstan | ||
| 4School of geosciences, D.Serikbayev east Kazakhstan Technical University, Ust-Kamenogorsk, Kazakhstan | ||
| چکیده | ||
| Diatomite is a naturally occurring siliceous sedimentary material characterized by high porosity, low density, developed pore architecture, and favorable adsorption properties, making it a promising low-cost sorbent for water and wastewater treatment applications. This review critically analyzes recent advances in the use of natural and modified diatomite for the removal of heavy metals, petroleum hydrocarbons, dyes, and emerging organic contaminants from aqueous systems. A systematic analysis of peer-reviewed literature indexed in Scopus and Web of Science was conducted, with emphasis on the physicochemical properties of diatomite, pollutant sorption mechanisms, and the influence of thermal and chemical activation methods on adsorption performance. The review demonstrates that the adsorption efficiency of natural diatomite is governed by its mineralogical composition, surface hydroxyl groups, pore accessibility, and environmental conditions such as pH, ionic strength, and temperature. Various modification approaches, including calcination, acid and alkaline activation, hydrothermal treatment, and surface functionalization, significantly improve the specific surface area, pore distribution, and density of active adsorption sites. Recent studies indicate that modified diatomite-based materials exhibit enhanced adsorption capacity and selectivity toward heavy metal ions, dyes, oils, and phenolic compounds compared with raw diatomite. Particular attention is given to thermo-chemical activation and composite materials incorporating magnetic phases, metal oxides, and biopolymers, which improve regeneration ability and practical applicability in real wastewater matrices. Despite the significant potential of activated diatomite, challenges remain regarding the heterogeneity of natural deposits, variability of experimental conditions, regeneration efficiency, and large-scale implementation. Overall, the review highlights diatomite as an environmentally sustainable and technologically versatile sorbent platform with considerable prospects for advanced water treatment technologies and circular environmental applications. | ||
| کلیدواژهها | ||
| Sorbent؛ Wastewater؛ Diatomite؛ Thermal modification؛ Water treatment | ||
| مراجع | ||
|
Abdel-Shafy, HI & Mansour, MS 2016, A review on polycyclic aromatic hydrocarbons: source, environmental impact, effect on human health and remediation. Egyptian Journal of Petroleum, 25(1): 107-123.
Alacabey, İ 2022, Endosulfan elimination using amine-modified magnetic diatomite as an adsorbent. Frontiers in Chemistry, 10: 907302.
Al-Qodah, Z, Lafi, WK, Al-Anber, Z, Al-Shannag, M & Harahsheh, A 2007, Adsorption of methylene blue by acid and heat treated diatomaceous silica. Desalination, 217(1-3): 212-224.
Aziz, KHH, Mustafa, FS, Omer, KM, Hama, S, Hamarawf, RF & Rahman, KO 2023, Heavy metal pollution in the aquatic environment: efficient and low-cost removal approaches to eliminate their toxicity: A review. RSC Advances, 13(26): 17595-17610.
Bilgin, M & Tulun, Ş 2015, Use of diatomite for the removal of lead ions from water: Thermodynamics and kinetics. Biotechnology & Biotechnological Equipment, 29(4): 696-704.
Brahimi, S, Hamadache, M & Hifi, M 2025, Sustainable treatment of Congo red by natural diatomite: Isotherm modeling and environmental health implications. Desalination and Water Treatment, 101415.
Bu, Z, Fang, Y, Chen, H, Zhang, M & Wang, F 2025, Study on the adsorption properties of organically modified diatomite for methylene blue. Scientific Reports, 15(1): 27561.
Caliskan, N, Kul, AR, Alkan, S, Sogut, EG & Alacabey, İ 2011, Adsorption of Zinc (II) on diatomite and manganese-oxide-modified diatomite: A kinetic and equilibrium study. Journal of Hazardous Materials, 193: 27-36.
da Silva, PLB, de Sousa, LDA, da Silva Pinheiro, V, Harima, E & Leite, JYP 2009, Caracterização da diatomita de Rio do Fogo–RN-Brasil. Holos, 3: 52-62.
Datsko, TYa, Zelentsov, VI & Dvornikova, EE 2011, Physicochemical and adsorption-structural properties of diatomite modified with aluminum compounds. Electronic Materials Processing, 47(6): 59–68.
ElSayed, EE 2018, Natural diatomite as an effective adsorbent for heavy metals in water and wastewater treatment (a batch study). Water Science, 32(1): 32-43.
Ersoy, O, Rençberoğlu, M, Karapınar Güler, D & Özkaya, ÖF 2022, A novel flux that determines the physico-chemical properties of calcined diatomite in its industrial use as a filler and filter aid: Thenardite (Na2SO4). Crystals, 12(4): 503.
Fathy, NA, Mousa, SM, Aboelenin, RM, Sherief, MA & Abdelmoaty, AS 2022, Strengthening the surface and adsorption properties of diatomite for removal of Cr (VI) and methylene blue dye. Arabian Journal of Geosciences, 15(22): 1664.
Gondek, K, Baran, A, Boguta, P & Bołdak, M 2024, The use of diatomite-based composites for the immobilization of toxic heavy metals in industrial wastes using post-flotation sediment as an example. Materials, 17(24): 6174.
Gondek, K, Micek, P, Baran, A, Bajda, T, Kowal, J, Lis, M & Smoroń, K 2023, Modified natural diatomite with various additives and its environmental potential. Materials, 16(12): 4494.
Guo, Z, Ren, Z, Gao, H, Guan, J, Li, P, He, Y & Chen, Z 2024, Hydrothermal modification of calcined diatomite with CaO: Effect of NaOH pretreatment. Materials Chemistry and Physics, 314: 128791.
Kato, S & Kansha, Y 2024, Comprehensive review of industrial wastewater treatment techniques. Environmental Science and Pollution Research, 31(39): 51064-51097.
Khaldi, K, Hadjel, M, Cherrak, R, Souidi, Z & Benyoucef, A 2018, Adsorption kinetics of an cationic dye ffrom aqueouse solution by Algerian mineral materials. Moroccan Journal of Chemistry, 6(2): J-Chem.
Khraisheh, MAM, Al-Ghouti, MA, Allen, SJ & Ahmad, MN 2005, Effect of OH and silanol groups in the removal of dyes from aqueous solution using diatomite. Water Research, 39(5): 922-932.
Kumar, R, Qureshi, M, Vishwakarma, DK, Al-Ansari, N, Kuriqi, A, Elbeltagi, A & Saraswat, A 2022, A review on emerging water contaminants and the application of sustainable removal technologies. Case Studies in Chemical and Environmental Engineering, 6: 100219.
Łach, M, Pławecka, K, Marczyk, J, Ziejewska, C, Hebdowska-Krupa, M, Nykiel, M & Smoroń, K 2023, Use of diatomite from Polish fields in sustainable development as a sorbent for petroleum substances. Journal of Cleaner Production, 389: 136100.
Lemessa, G, Chebude, Y, Demesa, AG, Fadeev, E, Koiranen, T & Alemayehu, E 2024, Development of suitable magnetite–diatomite nanocomposite for Cd (II) adsorptive removal from wastewater. Scientific African, 24: e02213.
Lenz, PE, Palm, SK, Nyamekye, GA, Humphreys, BS & Wang, Q 2022, U.S. Patent No. 11,243,177. Washington, DC: U.S. Patent and Trademark Office.
Lin, L, Yang, H & Xu, X 2022, Effects of water pollution on human health and disease heterogeneity: a review. Frontiers in Environmental Science, 10: 880246.
Mojiri, A, Zhou, J L, Ohashi, A, Ozaki, N & Kindaichi, T 2019, Comprehensive review of polycyclic aromatic hydrocarbons in water sources, their effects and treatments. Science of the Total Environment, 696: 133971.
Oladimeji, TE, Oyedemi, M, Emetere, ME, Agboola, O, Adeoye, JB & Odunlami, OA 2024, Review on the impact of heavy metals from industrial wastewater effluent and removal technologies. Heliyon, 10(23).
Olkowska, E, Ruman, M & Polkowska, Ż 2014, Occurrence of surface active agents in the environment. Journal of Analytical Methods in Chemistry, 2014(1): 769708.
Özen, İ, Şimşek, S & Okyay, G 2015, Manipulating surface wettability and oil absorbency of diatomite depending on processing and ambient conditions. Applied Surface Science, 332: 22-31.
Phong, MT, Hai, TD & Tuan, PD 2012, Effects of Fluxing Agents on Filter Aids Prepared from Lam-Dong Diatomate. ASEAN Journal of Chemical Engineering, 12(2).
Qasem, NA, Mohammed, RH & Lawal, DU 2021, Removal of heavy metal ions from wastewater: A comprehensive and critical review. Npj Clean Water, 4(1): 36.
Reka, AA, Pavlovski, B, Fazlija, E, Berisha, A, Pacarizi, M, Daghmehchi, M & Oral, A 2021, Diatomaceous Earth: Characterization, thermal modification, and application. Open Chemistry, 19(1): 451-461.
Ren, Z, Gao, H, Zhang, H & Liu, X 2014, Effects of fluxes on the structure and filtration properties of diatomite filter aids. International Journal of Mineral Processing, 130: 28-33.
Ren, Z, He, Y, Zheng, R, Guo, Z, Gao, H, He, X & Ji, X 2022, The preparation and characterization of calcined diatomite with high adsorption properties by CaO hydrothermal activation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 636: 128134.
Sagimbayeva, SZ, Shunkeyev, KS, Tarkovsky, VV, Herman, AE, Sergeyev, DM, Tastanova, LK & Ubayev, JK 2021, Electrohydraulic method of enrichment of natural diatomite from a Kazakhstan deposit. Engineering Journal of Satbayev University, 143(4): 138-150.
Shen, TM, Xu, H, Miao, Y, Ma, LL, Chen, NC & Xie, QL 2021, Study on the adsorption process of Cd (II) by Mn-diatomite modified adsorbent. Materials Letters, 300: 130087.
Sheng, G, Wang, S, Hu, J, Lu, Y, Li, J, Dong, Y & Wang, X 2009, Adsorption of Pb (II) on diatomite as affected via aqueous solution chemistry and temperature. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 339(1-3): 159-166.
Sheng, G, Wang, S, Hu, J, Lu, Y, Li, J, Dong, Y & Wang, X 2009, Adsorption of Pb (II) on diatomite as affected via aqueous solution chemistry and temperature. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 339(1-3): 159-166.
Shewatatek, S, Gonfa, G, Hailegiorgis, SM & Tessema, B 2025, Adsorptive removal of lead ions from wastewater using modified diatomite. Journal of Hazardous Materials Advances, 100900.
Smirnov, PV 2016, Results of comprehensive studies of the material composition of diatomites from the Irbit deposit. Bulletin of Tomsk Polytechnic University. Georesources Engineering, 327(6): 93-104.
Smirnov, PV, Zhakipbaev, BE, Staroselets, DA, Deryagina, OI, Batalin, GA, Gareev, BI & Vergunov, AV 2023, Diatomites and opoka from western Kazakhstan deposits: lithogeochemistry, structural and textural parameters, potential of use. Bulletin of the Tomsk Polytechnic University Geo Assets Engineering, 334(7): 187-201.
Sriram, G, Kigga, M, Uthappa, UT, Rego, RM, Thendral, V, Kumeria, T & Kurkuri, MD 2020, Naturally available diatomite and their surface modification for the removal of hazardous dye and metal ions: a review. Advances in Colloid and Interface Science, 282: 102198.
Sriram, G, Kigga, M, Uthappa, UT, Rego, RM, Thendral, V, Kumeria, T & Kurkuri, MD 2020, Naturally available diatomite and their surface modification for the removal of hazardous dye and metal ions: a review. Advances in Colloid and Interface Science, 282: 102198.
Stefanou, E, Kantiranis, N, Chatzicharalambous, K, Mytiglaki, C, Stamatakis, M & Georgiadis, G 2022, Diatomaceous silica in environmental applications: A case study from the lacustrine deposit of Limnos Island, Aegean Sea, Greece. Minerals, 12(5): 523.
Westacott, S, Planavsky, NJ, Zhao, MY & Hull, PM 2021, Revisiting the sedimentary record of the rise of diatoms. Proceedings of the National Academy of Sciences, 118(27): e2103517118.
Yu, W, Deng, L, Yuan, P, Liu, D, Yuan, W, Liu, P & Chen, F 2015, Surface silylation of natural mesoporous/macroporous diatomite for adsorption of benzene. Journal of Colloid and Interface Science, 448: 545-552.
Yu, Y, Hu, Z, Wang, Y & Gao, H 2017, Magnetic SN-functionalized diatomite for effective removals of phenols. International Journal of Mineral Processing, 162: 1-5.
Yuan, P, Liu, D, Tan, DY, Liu, KK, Yu, HG, Zhong, YH & He, HP 2013, Surface silylation of mesoporous/macroporous diatomite (diatomaceous earth) and its function in Cu (II) adsorption: The effects of heating pretreatment. Microporous and Mesoporous Materials, 170: 9-19.
Zhang, J, Ping, Q, Niu, M, Shi, H & Li, N 2013, Kinetics and equilibrium studies from the methylene blue adsorption on diatomite treated with sodium hydroxide. Applied Clay Science, 83: 12-16.
Zhao, Y, Tian, G, Duan, X, Liang, X, Meng, J & Liang, J 2019, Environmental applications of diatomite minerals in removing heavy metals from water. Industrial & Engineering Chemistry Research, 58(27): 11638-11652. | ||
|
آمار تعداد مشاهده مقاله: 17 تعداد دریافت فایل اصل مقاله: 26 |
||